About Atomic structure in A Level Chemistry
Atomic structure is one of the 18 main topics in our A Level Chemistry (Cambridge (CAIE) 9701) question bank, and about 4% of its real questions come from it. Tayyari Karo has 26 real questions on this topic from 2021 to 2026, from Paper 1, Paper 2; 21 are multiple choice and marked instantly, and the rest are structured questions with a model answer. By difficulty: 13 medium, 7 hard, 6 easy.
Work through the questions below, then open the explanation for each one. Redo the ones you missed a few days later.
Try 6 real questions
These are real past-paper questions. Think of your answer first, then open the explanation.
May/June 2026 · Paper 1 · Atomic structure
Why is the first ionisation energy of sulfur lower than that of phosphorus?
- Sulfur is more electronegative than phosphorus.
- Sulfur forms anions more readily.
- In sulfur, the electron lost is paired with another electron.
- The sulfur atom is larger than the phosphorus atom.
Show answer and explanation
Answer: C. In sulfur, the electron lost is paired with another electron.
In S the 3p electron removed is in a doubly occupied 3p orbital; electron-electron repulsion makes it easier to remove.
May/June 2025 · Paper 1 · Atomic structure
Which statement about a 3p orbital is correct?
- It can hold a maximum of six electrons.
- It has the highest energy of the orbitals with principal quantum number 3.
- It is at a higher energy level than a 3s orbital but has the same shape.
- It is occupied by one electron in an isolated phosphorus atom.
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Answer: D. It is occupied by one electron in an isolated phosphorus atom.
Phosphorus is 1s2 2s2 2p6 3s2 3p3, so each of the three 3p orbitals holds one electron (Hund's rule) — one electron in a given 3p orbital.
May/June 2024 · Paper 1 · Atomic structure
Which statement about ¹³¹₅₃I is correct?
- A negative ion of ¹³¹₅₃I contains 53 neutrons and 52 electrons.
- A negative ion of ¹³¹₅₃I contains 53 neutrons and 54 electrons.
- A negative ion of ¹³¹₅₃I contains 78 neutrons and 52 electrons.
- A negative ion of ¹³¹₅₃I contains 78 neutrons and 54 electrons.
Show answer and explanation
Answer: D. A negative ion of ¹³¹₅₃I contains 78 neutrons and 54 electrons.
neutrons = 131 − 53 = 78; I⁻ has one extra electron, so electrons = 53 + 1 = 54.
October/November 2023 · Paper 1 · Atomic structure
Sodium azide, NaN3, is an explosive used to inflate airbags in cars when they crash. It consists of positive sodium ions and negative azide ions. What are the numbers of electrons in the sodium ion and the azide ion (N3⁻)?
- sodium ion = 10, azide ion = 20
- sodium ion = 10, azide ion = 22
- sodium ion = 12, azide ion = 20
- sodium ion = 12, azide ion = 22
Show answer and explanation
Answer: B. sodium ion = 10, azide ion = 22
Na⁺ has 11−1=10 electrons; N3⁻ has (3×7)+1=22 electrons.
October/November 2022 · Paper 1 · Atomic structure
Which statement about the electrons in a ground state carbon atom is correct?
- Electrons are present in four different energy levels.
- There are more electrons in p orbitals than there are in s orbitals.
- The occupied orbital of highest energy is spherical.
- The occupied orbital of lowest energy is spherical.
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Answer: D. The occupied orbital of lowest energy is spherical.
Carbon is 1s²2s²2p²; the lowest energy occupied orbital, 1s, is spherical.
May/June 2021 · Paper 1 · Atomic structure
Why is the first ionisation energy of oxygen less than that of nitrogen?
- The nitrogen atom has its outer electron in a different subshell.
- The nuclear charge on the oxygen atom is greater than that on the nitrogen atom.
- The oxygen atom has a pair of electrons in one p orbital that repel one another.
- There is more shielding in an oxygen atom.
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Answer: C. The oxygen atom has a pair of electrons in one p orbital that repel one another.
Oxygen's 2p⁴ arrangement forces two electrons into one p orbital; their mutual repulsion makes one easier to remove than nitrogen's singly-occupied 2p³ arrangement.